Preparation and properties of AZO/PS/AZO tri-layer transparent conductive film with a light-trapping structure

The light-trapping structure is an effective method to increase solar light capture efficiency in the solar cells. In this study, Al-doped ZnO (AZO)/polystyrene (PS)/AZO tri-layer transparent conductive film with light-trapping structure was fabricated by magnetron sputtering and liquid phase methods. The structural, optical and electrical properties of the AZO films could be controlled by different growth conditions. When the sputtering pressure of the under-layer AZO film was 0.2 Pa, the discharge voltage was around 80 V, which was within the optimal process window for obtaining AZO film with high crystallinity. The optimal under-layer AZO film had a large surface roughness and a very low static water contact angle of 75.71°, promoting the relatively uniform distribution of PS spheres. Under this sputtering condition, the prepared AZO/PS/AZO tri-layer film had the highest crystallinity and least point defects. The highest carrier concentration and Hall mobility are 3.0 × 10²¹ cm^-3and 5.39 cm² V^-1 s^-1, respectively. Additionally, a transparent conductive film with the lowest resistivity value (3.88 × 10^-4 Ω cm) and the highest average haze value (26.5%) was obtained by optimizing the process parameters. These properties were comparable to or exceed the reported values of surface-textured SnO₂-based as well as ZnO-based TCOs films, making our films suitable for transparent electrode applications, especially in thin-film solar cells.     

Robust,low haze and graded porous anti-reflective glass by Tailoring the Nanostructures

Low haze and anti-reflective glass has high potential applications in automobile and optoelectronic fields. Etching is a novel and effective method to fabricate gradient refractive index anti-reflective layer on glass surface. However, the gradient layer on glass surface prepared by the etching method usually characterizes rough porous structure, and the structural defect results in high haze and low abrasion resistance to restrict its applications. In this paper, a hydrothermal etching method has been explored to prepare anti-reflective glass. It has demonstrated to be a new and facile method successfully to tailor the porous nanostructure of gradient refractive index layer and largely decrease the haze of the glass, by adding complex compound in the etching solution. Compared with the etching solution containing NaOH, adding the complex compound of C₆H₅Na₃O₇ in the etching solution has the advantage to overcome the defects. The grain diameter of the graded porous anti-reflective film decreases from ~63 nm to ~18 nm, the etched film thickness increases from 0.44 μm to 1.55 μm, the haze decreases drastically from 23.76% to 1.00%, the reflectivity decreases from 5.88% to 1.08% and the abrasion resistance greatly increases. However, when changing the complex compound from C₆H₅Na₃O₇ to Na₂HPO₄, the haze is 23.44% and has no effect on decreasing haze. Structural characterizations show that the grain size in the porous gradient layer can be easily tailored by changing the ion radius of complex anion in the etching solution, and the optical properties can be controlled. The paper provides new insights into the nanostructures and the preparation approach of anti-reflective glass.     

中国当代建筑集群设计现象研究

文章从研究“集群设计”的兴起与定位,历史渊源及其发展异化入手,进而探讨中国当代建筑集群设计的现象与概况, 并重点评述中国集群设计的特征、价值、意义与误区,以及与“明星建筑师”的关系     

Single-step process for transparent conductive ZnO:Ga films with uniform ultrahigh haze by oblique angle deposition

Increasing the haze of front electrodes of solar cells while retaining high optical transmittance is beneficial for increasing the power conversion efficiency. However, conventional methods of fabricating hazy films require additional etching steps or materials. Moreover, depositing large-area transparent conductive oxides with uniform ultrahigh haze is challenging. Here, we combine the oblique angle deposition and the atmospheric pressure plasma jet to produce GZO with a uniform ultrahigh haze of > 80% (non-uniformity ~1.35%), high transmittance of 88% (referenced to the substrate), and resistivity of 1.96 × 10^–3 Ω cm in a single step. We show that the high haze is caused by the “pre-deposition” of adsorbed particles on the bare substrate downstream and that the upstream dummy area should be avoided for high uniformity. Unlike existing methods, our method produces uniform films with ultrahigh haze and good transmittance in a single step without additional etching/ materials or changing parameters during operation.     

On the impact of haze on the yield of photovoltaic systems in Singapore

Anthropogenic haze, caused at least in parts by forest and agricultural land clearing fires in Sumatra (Indonesia), is occasionally causing air quality issues in Singapore, located 150–300 km east of the majority of these “hot spots”. The resulting air pollution partially blocks sunlight from reaching the ground, and consequently affects the electric power generation of solar photovoltaic (PV) systems in Singapore. In this work, a methodology is presented to estimate the haze-induced reduction of the light intensity reaching PV panels and the corresponding loss in the electric energy yield. An assessment of a major haze event in June 2013 is the basis for the loss analysis, which takes into account data filtering techniques in order to isolate cloudless conditions for inter-comparison between clear and hazy days. Data from previous years in non-hazy conditions serve as baseline for the determination of the clear sky conditions for Singapore. The novel method is further applied to investigate the power output of ten PV systems in Singapore during the June 2013 haze event. It is found that poor air quality levels during this event caused yield losses of PV systems in Singapore in the range of 15–25%.     

丁苯透明抗冲树脂雾度影响因素的研究

将抚顺的丁苯透明抗冲树脂SBC-03与美国菲利浦斯的KR-03等产品的雾度指标对比,通过对分子结构及工艺条件的分析及试验,找出了影响抚顺SBC-03雾度的因素,确定了抚顺SBC-03的适宜工艺条件,使抚顺SBC-03的雾度指标达到美国菲利浦斯产品的标准.     

Co-operation at work: a process-oriented perspective on joint activity in inter-organizational relations

In this paper the authors present a conceptual framework for analysing cooperation between organizations as a situated process, highlighting co-operation, co-ordination and co-construction as different modes of joint activity. Within this framework, the analysis of unexpected events becomes a crucial issue. The analytic power of reconstructing the (psycho-) logics of unexpected events in inter-organizational relations will be demonstrated in the presentation of selected outcomes of a research project on the dynamics of producer-supplier relationships in the German automobile industry. Also in this empirical part, the significance of trust and confidence in inter-organizational relations will be reflected.     

Preparation of Al-doped ZnO transparent electrodes suitable for thin-film solar cell applications by various types of magnetron sputtering depositions

In order to determine the influence of different types of magnetron sputtering (MS) depositions on the characteristics of Al-doped ZnO (AZO) thin films appropriate for applications as transparent electrodes in thin-film solar cells, transparent conducting AZO thin films were prepared on glass substrates at 200 °C by direct current (dc) magnetron sputtering (dc-MS), radio frequency (rf)-MS and rf power superimposed dc-MS (rf + dc-MS) depositions using an MS apparatus with the same AZO target. AZO thin films prepared by an rf + dc-MS deposition exhibited both a higher deposition rate than that found with rf-MS depositions and a lower resistivity or higher Hall mobility than those found with dc-MS. The lower dc sputter voltage featured in rf-MS and rf ± dc-MS depositions, producing smoother surface morphology and better crystallinity than obtained with dc-MS depositions. The light scattering characteristics of surface-textured AZO thin films prepared by various types of MS depositions were evaluated by observing the surface texture and measuring the optical transmittance and the diffusive component; wet-chemical etching of the thin film surface was performed in a 0.1% HCl solution. The obtainable haze property in the range from visible to near infrared in AZO films prepared by an rf + dc-MS deposition was markedly better than that obtained with dc-MS depositions.     

广州市灰霾监测颗粒物监测仪安装维护浅析

2008年广州市环境监测中心站成为了国家灰霍监测试点单位之一,并建立了灰霾监测试点实验室。灰霾的形成与细颗粒物PM2.5浓度有密切关系。实验室配置了美国赛默飞世尔公司新推出的1405-D双通道环境颗粒物监测仪对细颗粒物PM2.5和可吸入颗粒物PM10进行监测。本文着重介绍1405-D的安装、维护中容易出现的问题,并提出了一些维护经验和使用注意事项。希望为环境监测人员提供仪器安装和维护方面的参考,获得准确监测数据。经较长时间的使用维护,目前广州灰霾监测试点1405-D双通道环境颗粒物监测仪运行稳定。     

“雾霾事件”中京津冀地区公众健康与环境科普需求之研究

以北京市、天津市和河北省之农村和城市为目标调研,从公众需求视角分析该地区居民在需求媒介、需求内容和需求程度上的各种特征与趋势,为相关组织科普工作提供科学依据和建言。